What Is the Molecular Geometry of SO₃²⁻?

📚 Confused about how to draw SO₃²⁻ or determine its shape? You’re not alone. Sulfite ion problems show up frequently in General Chemistry and on ALEKS assignments — and they can be trickier than they look.

This guide will walk you through the full breakdown: Lewis structure, electron geometry, molecular geometry, hybridization, and polarity — all in one place.


🔬 Step 1: Lewis Structure of SO₃²⁻

  • Total valence electrons: 26 (6 from S + 6×3 from O + 2 from the -2 charge)
  • Central atom: Sulfur (S)
  • Arrangement: Three S–O single bonds and one lone pair on the sulfur
  • Resonance: The negative charge is delocalized over the three oxygen atoms via resonance

✅ This arrangement satisfies the octet rule for all atoms and allows resonance stabilization.

📐 Step 2: Electron Geometry

With three bonding domains and one lone pair around the central sulfur atom, the electron geometry is tetrahedral.

📐 Step 3: Molecular Geometry

Because one of the four electron regions is a lone pair, the actual molecular geometry becomes trigonal pyramidal.

Summary:
Electron Geometry = Tetrahedral
Molecular Geometry = Trigonal Pyramidal
Approximate Bond Angles = ~107.5°

🧪 Step 4: Hybridization

The central sulfur atom uses sp³ hybrid orbitals to accommodate the three sigma bonds and one lone pair.

🧲 Step 5: Polarity of SO₃²⁻

Because the molecular geometry is asymmetrical and the oxygen atoms are more electronegative, the sulfite ion is polar.

🎯 Real-World Examples of SO₃²⁻ Questions

Here are common ways SO₃²⁻ appears in chemistry courses:

  • “Draw the Lewis structure and determine the molecular geometry of SO₃²⁻.”
  • “Is SO₃²⁻ polar or nonpolar?”
  • “What is the hybridization of the central atom in SO₃²⁻?”

💡 Pro Tip: Know Your Geometry Names

Don’t confuse electron geometry with molecular geometry:

  • Electron geometry considers all electron domains (bonds and lone pairs)
  • Molecular geometry only considers bonded atoms

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🔗 Related Pages


❓ FAQ: SO₃²⁻ Molecular Geometry

Q: Is SO₃²⁻ trigonal planar?

No. Trigonal planar geometry occurs when there are three bonding groups and no lone pairs. SO₃²⁻ has one lone pair on sulfur, making it trigonal pyramidal.

Q: What is the bond angle in SO₃²⁻?

Approximately 107.5°, due to the repulsion caused by the lone pair on the central sulfur atom.

Q: What type of hybridization is used in SO₃²⁻?

sp³ hybridization, due to the four electron domains (three bonds + one lone pair).

Q: Is SO₃²⁻ polar or nonpolar?

Polar. The shape is asymmetrical, and the oxygen atoms pull electron density unevenly.

Q: How many resonance structures does SO₃²⁻ have?

Three equivalent resonance structures, where the negative charge is delocalized among the oxygen atoms.

Q: Can you do my SO₃²⁻ assignment for me?

Yes! Whether it’s an ALEKS module, MasteringChemistry question, or full chemistry class, our experts are ready. Submit your assignment.


🎓 Bottom Line

The molecular geometry of SO₃²⁻ is trigonal pyramidal, shaped by three bonding pairs and one lone pair on the sulfur. If this topic is confusing, you’re not alone — it’s one of the most commonly misunderstood ions in General Chemistry.

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